Nitrogen: Difference between revisions
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<b>Nitrogen</b> is a [[chemical element]]; in the [[periodic table]] it has symbol N and atom number 7. |
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'''Physical properties''' |
'''Physical properties''' |
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'''Chemistry''' |
'''Chemistry''' |
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Nitrogen is a [[non-metal]], with an [[electronegativity]] of 3.0. It has |
Nitrogen is a [[non-metal]], with an [[electronegativity]] of 3.0. It has five [[electrons]] in its outer shell, so is trivalent in most compounds. Pure nitrogen is an unreactive colorless [[diatomic]] gas at room temperature, and comprises about 2/3 of the [[Earth]]'s atmosphere. It condenses at 77 K and freezes at 63 K. Liquid nitrogen is a common [[cryogen]]. |
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The main hydride of nitrogen is [[ammonia]] (NH<sub>3</sub>) although [[hydrazine]] (N<sub>2</sub>H<sub>4</sub>) is also well known. Ammonia is somewhat more basic than [[water]], and in solution forms [[ammonium]] [[ion|ions]] (NH<sub>4</sub><sup>+</sup>). Liquid ammonia in fact slightly amphiprotic and forms ammonium and [[amide]] ions (NH<sub>2</sub><sup>-</sup>); both amides and [[nitride]] (N<sup>3-</sup>) salts are known, but decompose in water. |
The main hydride of nitrogen is [[ammonia]] (NH<sub>3</sub>) although [[hydrazine]] (N<sub>2</sub>H<sub>4</sub>) is also well known. Ammonia is somewhat more basic than [[water]], and in solution forms [[ammonium]] [[ion|ions]] (NH<sub>4</sub><sup>+</sup>). Liquid ammonia in fact slightly amphiprotic and forms ammonium and [[amide]] ions (NH<sub>2</sub><sup>-</sup>); both amides and [[nitride]] (N<sup>3-</sup>) salts are known, but decompose in water. |
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External Link: |
'''External Link:''' |
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Los Alamos National Laboratory's Chemistry Division: Periodic Table - Nitrogen |
*Los Alamos National Laboratory's Chemistry Division: Periodic Table - Nitrogen |
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**http://pearl1.lanl.gov/periodic/elements/7.html |
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See: [[Periodic Table]] |
See: [[Periodic Table]] |
Revision as of 15:43, 25 February 2002
Nitrogen is a chemical element; in the periodic table it has symbol N and atom number 7.
Physical properties
By far the most common isotope of nitrogen is 14N, which is produced in the CNO cycle in stars. Others undoubtedly include 15N and maybe even 13N...help.
Chemistry
Nitrogen is a non-metal, with an electronegativity of 3.0. It has five electrons in its outer shell, so is trivalent in most compounds. Pure nitrogen is an unreactive colorless diatomic gas at room temperature, and comprises about 2/3 of the Earth's atmosphere. It condenses at 77 K and freezes at 63 K. Liquid nitrogen is a common cryogen.
The main hydride of nitrogen is ammonia (NH3) although hydrazine (N2H4) is also well known. Ammonia is somewhat more basic than water, and in solution forms ammonium ions (NH4+). Liquid ammonia in fact slightly amphiprotic and forms ammonium and amide ions (NH2-); both amides and nitride (N3-) salts are known, but decompose in water.
Another kind of nitrogen anions are azides (N3-), which are linear and isoelectronic to carbon dioxide. Another molecule of the same structure is dinitrogen monoxide (N2O), or laughing gas. This is one of a variety of oxides, the most prominent of which are nitrogen monoxide (NO) and nitrogen dioxide (NO2), which both contain an unpaired electron. The latter shows some tendency to dimerize and is an important component of smog.
The more standard oxides, dinitrogen trioxide (N2O3) and dinitrogen pentoxide (N2O5), are actually fairly unstable and explosive. The corresponding acids are nitrous (HNO2) and nitric acid (HNO3), with the corresponding salts called nitrites and nitrates. Nitric acid is one of the few acids stronger than hydronium and its salts including some important minerals, like salt peter.
External Link:
- Los Alamos National Laboratory's Chemistry Division: Periodic Table - Nitrogen
See: Periodic Table